chemistry - valency

Q: Metal ‘M’ forms a peroxide of the type MO2, Valency of the metal wrt oxygen is? Doubt: ik generally it is +2 but if we take an example like sodium peroxide won’t we take the valency of the sodium to be +1 bc I have never seen Na have a charge +2, is it an exception case ? Excuse me if I am missing a stupid point
16 Replies
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g-sus
g-sus7mo ago
peroxide has a valency of 2 because of the way the oxygen atoms are bonded in it, hence u will need 2 Na 1+ ions to bond with it and make it neutral for the structure of peroxide: only 1 covalent bond is formed between the oxygen atoms and both atoms will have an empty space and accept 1 electron (ionic) each (hence 2 valency) @stormycloud
g-sus
g-sus7mo ago
isnt it like sodium and magnesium only the others in group 1 form superoxides or just oxides
iTeachChem
iTeachChem7mo ago
lower ones, yea down the group form superoxides as well rather Na and Mg do NOT form superoxides reason is in jd lee (kindaxD)
g-sus
g-sus7mo ago
nono i said they form peroxides, the others form superoxides
g-sus
g-sus7mo ago
i didnt know the ones below could form peroxides, i looked into it now i did self study of s block before school started, ig i missed this
iTeachChem
iTeachChem7mo ago
nice that you did this! if you wanna look up stuff for jee adv, jd lee is a good resource
stormycloud
stormycloudOP7mo ago
Tysm, I asked this to sir today and he explained as well So for valency of M won’t it be 1? Or am I missing something
g-sus
g-sus7mo ago
ill wait for inorganic to start in school, and ill simultaneously solve jd lee then 👍 this case M has valency 2 since 1 ion of M is required to balance out the peroxide (which requires 2 electrons)
stormycloud
stormycloudOP7mo ago
Wait why am I so stupid Thankyou so much, I have been overthinking this for no reason 🧍🏽‍♀️ +solved @g-sus @iTeachChem
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