Last minute chem doubts

I'm blanking like hell here so, couple of rapid fire doubts. 1. What are the deciding factors for melting point and boiling point of compounds? Specifically substituted benzenes. When does dipole moment come into play and when is it important to consider H-bonding? 2. For hybridisation of orbitals (or LCAO, whichever one you prefer), how does one decide which orbitals hybridise from a given set? Eg: For a sp³d hybridisation, can we know which d orbital is chosen? The d orbitals are initially degenerate so, what criterion applies? I thought I had these in notes, but apparently I don't. 🤷‍♂️
27 Replies
iTeachChem Helper
@Dexter
iTeachChem Helper
Note for OP
+solved @user1 @user2... to close the thread when your doubt is solved. Mention the users who helped you solve the doubt. This will be added to their stats.
Opt
OptOP4w ago
@iTeachChem sorry for the ping but could you help with the second doubt?
iTeachChem
iTeachChem4w ago
never bro ping anytime i think it has to do with the spacial orientatation of the d orbitals
iTeachChem
iTeachChem4w ago
Ligand field theory
Ligand field theory (LFT) describes the bonding, orbital arrangement, and other characteristics of coordination complexes. It represents an application of molecular orbital theory to transition metal complexes. A transition metal ion has nine valence atomic orbitals - consisting of five nd, one (n+1)s, and three (n+1)p orbitals. These orbitals ...
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iTeachChem
iTeachChem4w ago
for 1 - mug data. being real wtih you. if you go with logic, thre will be exceptions.
Opt
OptOP4w ago
...the exam is tomorrow.
Nimboi [ping if answering]
boiling point: hydrogen bonding, van der waal interactions, etc etc attractive forces basically uhh wait
Nimboi [ping if answering]
BYJUS
Boiling Points of Functional Groups: Introduction, Factors affectin...
Boiling Points of Functional Groups: When different functional groups are attached to the hydrocarbon, it changes the intramolecular force of attraction between the molecule, thus changing the boiling point of the molecule. The larger the force of attraction between the molecules the more would be its boiling point.
Nimboi [ping if answering]
also, more carbon atoms (longer chain) => more van der waal => more boiling point
SirLancelotDuLac
In melting point as far as I remember (not sure so take with a grain of salt) it depends on symmetry/packing, dipole moment, van der waal interactions and H-bonding.
iTeachChem
iTeachChem4w ago
lol then get off discord yo wait WAIT HOW IS THIS WORKING
Dexter
Dexter4w ago
😭😭
Nimboi
Nimboi4w ago
arey kya hua 😭
Opt
OptOP4w ago
Byju's site Ok, one more thing. ∆<P → WFL ∆>P → SFL ∆=P hua toh?
iTeachChem
iTeachChem4w ago
लोल
Opt
OptOP4w ago
? Kyun lol? There's an equal probability of pairing happening and not happening na? What happens then?
Opt
OptOP4w ago
Not that I know of.
Cakey Bot
Cakey Bot4w ago
iteachchem
Transcription requested by hithav
अरे मतलब that's a hypothetical situation that you are thinking of. Are there any real world examples? अगर है, then great. अगर नहीं है, then that's just a hypothetical thing that you are talking about.
Nimboi [ping if answering]
its essentially just a spectrum innit you can call it neutral field ligand for all it matters
Opt
OptOP3w ago
Supe Bowl bhi hoga kya?
Nimboi [ping if answering]
wha? super bowl?
Opt
OptOP3w ago
NFL
Nimboi [ping if answering]
kamedi 🗣️ 🔥
Opt
OptOP3w ago
+solved @Nimboi [ping if answering] @iTeachChem
iTeachChem Helper
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