hydrocarbons

arrange the following compounds in correct order of rate of decarboxylation methanoic acid ethanoic propanoic benzoic
12 Replies
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hardcoreisdead
hardcoreisdeadOP3w ago
from my understanding we have to compare stability of carbanion benzoic acid > metha>eth>prop hona chahiye then but given ans is benzoic>eth>prop>meth
Opt
Opt3w ago
Methanoic acid doesn't have a carbanion. It can't decarboxylate at all, it can only be oxidised. It's formic acid na?
hardcoreisdead
hardcoreisdeadOP3w ago
yepp how to compare then
Opt
Opt3w ago
You got the rest right It's just that formic acid can't be decarboxylated at all
hardcoreisdead
hardcoreisdeadOP3w ago
so its automatically at the end ? what bout this tho
Opt
Opt3w ago
Yes
hardcoreisdead
hardcoreisdeadOP3w ago
given ans is wrong then ?
Opt
Opt3w ago
Given is correct Benzoic because resonance stability, then acetic and propanoic based on chain length, then formic because it cannot be decarboxylated in the first place.
hardcoreisdead
hardcoreisdeadOP3w ago
alr got it +solved @Opt
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