I
iTeachChem•2mo ago
Nimboi

Chemical kinetics, factors affecting activation energy

My sample paper says activation energy is affected by: * surface area of the reactants * physical state * temperature * catalyst
13 Replies
iTeachChem Helper
iTeachChem Helper•2mo ago
@Dexter
iTeachChem Helper
iTeachChem Helper•2mo ago
Note for OP
+solved @user1 @user2... to close the thread when your doubt is solved. Mention the users who helped you solve the doubt. This will be added to their stats.
Nimboi
NimboiOP•2mo ago
i disagree with surface area and temperature surface area doesn't change the reaction itself right and in arrhenius equation activation energy is fixed and thus independent of temperature catalyst i agree physical state i'm not sure am i correct or nah
iSoham
iSoham•2mo ago
we'll wait for someone to confirm for surface area For temperature, note that many questions tell you to "assume" activation energy is constant for all temperature when using the arhenius quation
Nimboi
NimboiOP•2mo ago
ah 💀 nice catch thanku hang on a higher temperature means that energy is being supplied for the reaction right it doesn't mean that the reaction itself requires less energy, just that the energy is available in the environment nvm im confusing heat with temperature the temp. dependency makes sense
iSoham
iSoham•2mo ago
I dont know which book you can refer, but im pretty sure Ea changes with larger temperature changes
Nimboi
NimboiOP•2mo ago
yus google pe kuch mil jayega
itsav23
itsav23•2mo ago
i think surface area one is thoda galat....like it doesnt directly affect ea but if the medium is let's say sold and gas ya solid and liq then a larger surface area exposes more ractive sites which can indirectly influence how rxn proceeds. and won't it be independent of temp..like it doesn't change ea itself just the fraction of molecules that have enough energy to react. (correct me if im wrong )
generic display name
generic display name•2mo ago
Surface area ke baare mein kuch toh concept that surface chemistry mei More the surface area, more reaction sites are available for reaction to take place Hence it is recommended to take reactants in the powdered form (if we consider key and lock mechanism as an illustration)
Nimboi
NimboiOP•2mo ago
yeh i used the same reasoning atp we're getting into the definition of activation energy, and whether it means the amount of energy required or the extra amount of energy required that it doesn't already have if its the first option, Ea is temperature independent and if its the second option, Ea is temperature dependent
Prachi
Prachi•2mo ago
It's extra amount of energy So, Ea is temperature dependent
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Nimboi
NimboiOP•2mo ago
ahh this is nice thank you, explains everything +solved prachi1308 isoham itsav23 "Flame Tests Lover"
iTeachChem Helper
iTeachChem Helper•2mo ago
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