I
iTeachChem•2mo ago
Nimboi

d-block, Exchange energy

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12 Replies
iTeachChem Helper
iTeachChem Helper•2mo ago
@Dexter
iTeachChem Helper
iTeachChem Helper•2mo ago
Note for OP
+solved @user1 @user2... to close the thread when your doubt is solved. Mention the users who helped you solve the doubt. This will be added to their stats.
Nimboi
NimboiOP•2mo ago
what does this line mean? also, i'd appreciate it if someone could simplify this exchange energy concept for me
Opt
Opt•2mo ago
Go to chemical bonding in 11th NCERT. Green box at the end of the chapter.
Nimboi
NimboiOP•2mo ago
oke did you mean atomic structure
Opt
Opt•2mo ago
Ok wait yeah Atomic structure
Nimboi
NimboiOP•2mo ago
No description
Nimboi
NimboiOP•2mo ago
why would a d(6,7,8 or 9) orbital have less exchange energy than a d5 orbital i'd think more parallel spin electrons meant more exchange energy
iTeachChem
iTeachChem•2mo ago
well this is in bsc man in detail. the short version is - anything at the microscale has to do with probability so, if something has more states in which it can exist in, higher is its stability. This is how statistical thermodynamics works, and is also the basis of entropy and microstates. I am going to stop here, you can read up more on this online, but since the 5 electrons are equivalent and can exchange each others position, it makes them more stable, similarly with 10. very crude explanation, I know :D read what I wrote above :) all electrons are not equivalent, 8 and 9 would have some paired, some unpaired.
iTeachChem
iTeachChem•2mo ago
Physics Stack Exchange
What is the “exchange energy of electrons”?
First, do not try to give me the perplexing explanations involving higher QM. I am new to QM, so please give a gentle explanation. Now, my textbook see page 36 states that electrons of degenerate
Nimboi
NimboiOP•2mo ago
oh damn ok i love this person going "gentle explanation pls 🙏" twice such a mood yeah this would require me to go into a lot of detail but its quite interesting thankyou :) +solved Opt iTeachChem
iTeachChem Helper
iTeachChem Helper•2mo ago
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