Fajan's Rules

Why is the answer not BaCl2(more +ve charge means more covalent character right?)
No description
18 Replies
iTeachChem Helper
@Dexter
iTeachChem Helper
Note for OP
+solved @user1 @user2... to close the thread when your doubt is solved. Mention the users who helped you solve the doubt. This will be added to their stats.
Say_miracle_shadow
I'm not sure but this is what i got
No description
Say_miracle_shadow
n size of Ag+<Ba2+ so if cation's size increases the covalent character decreases and hence ionic chr increases
Percy
PercyOP2mo ago
is K+ smaller than Ag+
Nimboi
Nimboi2mo ago
considerably look at the atomic numbers 19 and 47
Percy
PercyOP2mo ago
then shouldn't KCl be the most ionic
Nimboi
Nimboi2mo ago
yeah but the question asked least ionic Ba has a +2 charge but is larger than Ag for least ionic, you need: * less charge on the cation and anion * bigger cation * smaller anion if the answer's AgCl then charge is the dominating factor rather than size never trust AI summaries charge dominates over size https://old.reddit.com/r/chemhelp/comments/1hi1b9p/question_fajans_rule_priority/ (+ proof by electrostatics in the comments) google's AI especially is really bad
Percy
PercyOP2mo ago
sorry I meant to type most covalent I thought according to Fajan's rules, covalent character depends on: 1. Smaller size of cation 2. More Charge of Cation 3. Larger Anion If a compound has more covalent character then it's ionic character decreases kindly excuse me if I botched up the concept
Prachi
Prachi2mo ago
More zeff, More polarizing power, more covalent character, less ionic character
No description
Percy
PercyOP2mo ago
thanks
_zbro
_zbro2mo ago
the SCLA trick works always.
Prachi
Prachi2mo ago
S for size, C for charge, A for atomicity but what about L
SirLancelotDuLac
Isn't it because Ag+ is pseudo inert configuration?
Say_miracle_shadow
idk but ig Lattice energy
iTeachChem
iTeachChem2mo ago
this is it doston. please close it out :) @Percy Thanks for the detailed response! Cool notes.
Percy
PercyOP4w ago
+solved @SirLancelotDuLac @Prachi @_zbro @Nimboi
iTeachChem Helper
Post locked and archived successfully!
Archived by
<@714440046429601792> (714440046429601792)
Time
<t:1739206151:R>
Solved by
<@1075951732460376214> (1075951732460376214), <@926887811674673172> (926887811674673172), <@923570231346089994> (923570231346089994), <@717724055217635398> (717724055217635398)

Did you find this page helpful?