Hydride shift (?)

why would carbocation not rearrange to give option (d) (attatched my working)
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iTeachChem Helper
Hello @manas!
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simplybear
simplybear3mo ago
i believe its because of ngp im not sure of the mechanism
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Is B the answer? I assume that the H+ will attack on benzene first, then the cyclopropyl ring will neutralize the positive charge on benzene ring to form product in (B). It's a perfectly aromatic system if you see. Benzene pe negative charge aayega (Ph- is still aromatic as this negative charge is localised and doesn't participate in resonance) and cyclopropenium cation is formed which is stable due to dancing resonance
iTeachChem
iTeachChem2mo ago
sorted?^
manas
manasOP2mo ago
yes sir, thank you apolgogies to all those who replied for not checking earlier
iTeachChem
iTeachChem2mo ago
Can you please close it out? Check the pinned thread in the doubts section on how to do so :)
manas
manasOP2mo ago
+solved @Flame Tests Lover
iTeachChem Helper
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