ISOMERISM

No description
No description
22 Replies
iTeachChem Helper
iTeachChem Helper•3d ago
@Dexter
iTeachChem Helper
iTeachChem Helper•3d ago
Note for OP
+solved @user1 @user2... to close the thread when your doubt is solved. Mention the users who helped you solve the doubt. This will be added to their stats.
cauchyschwartz
cauchyschwartzOP•3d ago
if (C) is planar how id (D) non planar dono central Carbon sp hybridised
Opt
Opt•3d ago
We aren't considering lone pairs on oxygen, but we do consider the hydrogens on a carbon. So, even though in both cases the hybridization is the same, in D, the two pairs of hydrogens are in mutually perpendicular planes. In C, there is only one plane in consideration in the first place.
cauchyschwartz
cauchyschwartzOP•3d ago
No description
cauchyschwartz
cauchyschwartzOP•3d ago
i am so confused oh but what about this
SirLancelotDuLac
SirLancelotDuLac•3d ago
Let p_x orbital of middle carbon makes a pi bond with carbon in d, then only p_y orbital of carbon can make pi cond with the other carbon. Also p-z p-z ki overlapping makes sigma bond between carbons. Now one CH2 group is in the horizontal (x-z) plane one is in the vertical (y-z)
Opt
Opt•3d ago
No description
Opt
Opt•3d ago
Messy diagram, but I hope you get it
cauchyschwartz
cauchyschwartzOP•3d ago
i understand d but isnt the same with C yeh
Opt
Opt•3d ago
We don't care about if the l.p.s are in the same plane or not
SirLancelotDuLac
SirLancelotDuLac•3d ago
C wale mein there is no hydrogen or stuff attached to O
Opt
Opt•3d ago
We just consider atoms in plane
SirLancelotDuLac
SirLancelotDuLac•3d ago
Only lone pairs.
cauchyschwartz
cauchyschwartzOP•3d ago
could u make a better diagram of C if mine is wrong idk 🥺
SirLancelotDuLac
SirLancelotDuLac•3d ago
This is fine ig. (Just draw the lone pairs on oxygen tho)
cauchyschwartz
cauchyschwartzOP•3d ago
but doesnt this indicate ki yeh non planar hai? arent the blue and red ones in planes perpendicular to each other?
Opt
Opt•3d ago
Yup And purple is in the plane of the blue orbitals Oh crap Wait i made a mistake
cauchyschwartz
cauchyschwartzOP•3d ago
toh fir how is the entire thing in the same plane oo
Opt
Opt•3d ago
H, H, C, C, O are in the same plane. Only the pi bonds and lone pairs are out of plane And those don't matter.
cauchyschwartz
cauchyschwartzOP•3d ago
how is that matlab this is wrong? acha
S2_zBro#8929
S2_zBro#8929•3d ago
In allenes, the arrangement becomes perpendicular alternatively per d..b.

Did you find this page helpful?