Vant hoff Factor

Why cant we just take 2 cases 1 dissciation with alpha = 0.5 and 2nd dimerize with alpha 0.5 that way ans is coming 225 but ans is 125
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18 Replies
iTeachChem Helper
@Dexter
iTeachChem Helper
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iTeachChem
iTeachChem8mo ago
Can you show the calc here? What is the overall i basically? 1.25 is what i am getting
Gamertug
GamertugOP8mo ago
my ans comes out to be 2.25 if i do it seprately thats the ans
Real potato
Real potato8mo ago
Direct formula wont work here here you need to use i=total no of particles after dissociation/association divided by initial no of particles
iTeachChem
iTeachChem8mo ago
Can you show us how? Take it as 1 mole. So 0.5 moles halves to 0.25 and rest doubles to 1
Gamertug
GamertugOP8mo ago
I1 = 1 + (n-1)a a=0.5 i2 = 1 -a + a/n a=0.5
iTeachChem
iTeachChem8mo ago
Final particles - 1.25 Initial particles 1 Never use this formula please. Humble suggestion
Gamertug
GamertugOP8mo ago
why?
iTeachChem
iTeachChem8mo ago
First principles. Alqays. Case in point :)
Gamertug
GamertugOP8mo ago
using those reactions and writing moles that stuff?
iTeachChem
iTeachChem8mo ago
Watch my sessions. I explain how easy it is to do things from first principles. Yes
Gamertug
GamertugOP8mo ago
which one
iTeachChem
iTeachChem8mo ago
See this. i = actual particles by initial.
Gamertug
GamertugOP8mo ago
oh ok thx
iTeachChem
iTeachChem8mo ago
Solutions. On my bio here.
Gamertug
GamertugOP8mo ago
+solved @iTeachChem
iTeachChem Helper
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