Diazonium compounds Class 12

Hey, how does orthoamino aniline + HNO2 and H+ ions give benzotriazole? Could someone explain the mechanism behind it?
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11 Replies
iTeachChem Helper
@Dexter
iTeachChem Helper
Note for OP
+solved @user1 @user2... to close the thread when your doubt is solved. Mention the users who helped you solve the doubt. This will be added to their stats.
iTeachChem
iTeachChem7mo ago
Editorial Team
Labmonk
Synthesis of Benzotriazole
Benzotriazole can be prepared by treating o-phenylenediamine with nitrous acid (liberated during the reaction between sodium nitrite and
iTeachChem
iTeachChem7mo ago
One suggestion when you are posting a doubt, you can put the name of the concept and chapter in the post heading. That way it will be easy to find later on.
iTeachChem
iTeachChem7mo ago
right now it shows up as confused xD which will be hard to search if you need to search for it 6 months down the line :P
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iTeachChem
iTeachChem7mo ago
wait aapne bhi mechanisam likha toh tha? the N behaves as a base, giving electrons to HNO2, process repeats with the other N from NH2
PeterGriffinItis
PeterGriffinItisOP7mo ago
Sure sir The mechanism that I have written? Is that it? I saw the mechanism and jotted it down in brief.. But couldn't figure out the reason for it
iTeachChem
iTeachChem7mo ago
the acid part (first step ) elaborate karna hoga check the links jo share kiye, the electron pair from NH2 attacks the HNO2 ka N. And then repeat from the other NH2 Is this alright @PeterGriffinItis ?
PeterGriffinItis
PeterGriffinItisOP7mo ago
Yes sir absolutely +solved @iTeachChem
iTeachChem Helper
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