Stability order GOC

this is the increasing order of the stability i think i got the right stuff i cant differentiate between the stability of phenyl radical thing and the second one from left
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21 Replies
iTeachChem Helper
@Dexter
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ywp nice
Weirdo
WeirdoOP10mo ago
thats cool (just a suggestion ping after 10 minutes of inactivity in a forum would be better imo )
Maven
Maven10mo ago
Perhaps we can deal it with Inductive effect...
Weirdo
WeirdoOP10mo ago
not sure how will that work
Maven
Maven10mo ago
Same...still finding some way... Well I think...look at the hybridization Sp2 carbon ki electronegativity is greater than sp3 carbon to us par free radical(which for ease works similar to a positive charge) is more unstable and first Wale compound mein on addition to that -I of double bond is destabilizing it even more...
Weirdo
WeirdoOP10mo ago
in both first two casses in which i have confusion in has the free radical on a sp2 carbon they both are unstable but why is the left most the most unstable
Maven
Maven10mo ago
Mean? Actually Electronegativity goes hand in hand with -I here I think baaki hamare sir ne to Aisa karne ko bola ha, as EN increase, stability of neg charge increase and positive charges become more unstable, free radical ko positive charge manke kar lete
Weirdo
WeirdoOP10mo ago
yeah thats ok and cool but i cant seem to set it here (one sec attaching image , im on slowmode)
Maven
Maven10mo ago
Sure...
Weirdo
WeirdoOP10mo ago
like can you explain using your logic while describing each of these one by one im not able to recoup the info ig
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!Nimay¡
!Nimay¡10mo ago
Less alpha hydrogens less hyperconjugation
Weirdo
WeirdoOP10mo ago
yeah noticed that for some reason i was thinking resonance in the first one doubts solved now thanks!
Maven
Maven10mo ago
I don't think here we need to consider +H effect...can't go through-I?
!Nimay¡
!Nimay¡10mo ago
H is a stronger effect
Maven
Maven10mo ago
2 mein hyperconjucation ho hi nhi rha as free radical is present in sp2 orbital and is in the plane of the ring So...the only way is inductive dude...I guess. Perhaps m wrong...but this is what makes sense to me.
iTeachChem
iTeachChem10mo ago
yo @Weirdo is this one done?
Weirdo
WeirdoOP10mo ago
oh yeah my bad sorry
iTeachChem
iTeachChem10mo ago
+solved @!Nimay¡
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